ملخص
DFT calculations point out that the photo-oxidation of water on GaN is energetically considerably facilitated by adsorbed carbonate. As the redox potential of the couple CO3.-/CO32- is considerably lower than that of the couple OH./OH- but still enables the oxidation of water it is suggested that carbonate should be considered as a catalyst/co-catalyst in a variety of catalytic/photo-catalytic/electro-catalytic oxidation processes.
اللغة الأصلية | الإنجليزيّة |
---|---|
الصفحات (من إلى) | 11069-11072 |
عدد الصفحات | 4 |
دورية | Physical Chemistry Chemical Physics |
مستوى الصوت | 18 |
رقم الإصدار | 16 |
المعرِّفات الرقمية للأشياء | |
حالة النشر | نُشِر - 28 أبريل 2016 |