TY - JOUR
T1 - The electrochemical oxidation of divalent nickel complexes with tetra-aza-macrocyclic ligands in aqueous solutions
AU - Zeigerson, Esther
AU - Ginzburg, Gregory
AU - Kirschenbaum, Louis J.
AU - Meyerstein, Dan
N1 - Funding Information:
This study was supported in part by the United States-Israel Binational Science Foundation (B.S.F.) Jerusalem, Israel. A fellowship to E.Z. from the A.K. Casali Foundation is appreciated. Thanks are due to Dr. S. Maniv of the Physics Dept., Ben-Gurion University of the Negev, for preparation of electrodes.
PY - 1981/10/9
Y1 - 1981/10/9
N2 - The electrochemical oxidation of three divalent nickel complexes with tetra-aza-macrocyclic ligands in perchlorate- and sulphate-containing aqueous solutions is reported. The mechanism of oxidation is analysed in detail. Redox potentials, diffusion coefficients, a transfer coefficient and a heterogeneous rate constant are reported. The pH effect on the electrochemical oxidations is discussed.
AB - The electrochemical oxidation of three divalent nickel complexes with tetra-aza-macrocyclic ligands in perchlorate- and sulphate-containing aqueous solutions is reported. The mechanism of oxidation is analysed in detail. Redox potentials, diffusion coefficients, a transfer coefficient and a heterogeneous rate constant are reported. The pH effect on the electrochemical oxidations is discussed.
UR - https://www.scopus.com/pages/publications/2542549068
U2 - 10.1016/S0022-0728(81)80472-X
DO - 10.1016/S0022-0728(81)80472-X
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AN - SCOPUS:2542549068
SN - 0022-0728
VL - 127
SP - 113
EP - 126
JO - Journal of Electroanalytical Chemistry
JF - Journal of Electroanalytical Chemistry
IS - 1-3
ER -