Synthetic and Mechanistic Study of the Catalytic Enantioselective Preparation of Primary β-Amino Ketones from Enones and a Fluorinated Gabriel Reagent

Keyphrases

• Activation Mechanism 33%
• Aluminium(I) 33%
• Ammonia Equivalent 33%
• Asymmetric 1,4-addition 33%
• Catalytic Asymmetric Reaction 33%
• Chemoselective 33%
• Dual Activation 33%
• Enantioselectivity 100%
• Enones 100%
• Fluorinated 100%
• Further Development 33%
• Gabriel 100%
• Mechanistic Studies 100%
• Oxo Complexes 33%
• Percentage Yield 33%
• Pre-equilibrium 33%
• Primary Amines 33%
• Rate-determining Step 33%
• Salen 33%
• Synthetic Study 100%
• Unsaturated Ketones 33%
• β-amino Ketones 100%

Chemistry

• Aluminum 33%
• Chemoselectivity 33%
• Enone 100%
• formation 33%
• Ketones 100%
• Mechanistic Study 100%
• Primary Amine 33%
• Rate-Determining Step 33%
• Salen 33%