Synthesis of axially chiral 1,8-diarylnaphthalene ligands and application in asymmetric catalysis: An intriguing fluorine effect

Harisadhan Ghosh; Ravishashidhar Vavilala; Alex M. Szpilman

doi:10.1016/j.tetasy.2014.12.008

Synthesis of axially chiral 1,8-diarylnaphthalene ligands and application in asymmetric catalysis: An intriguing fluorine effect

Harisadhan Ghosh
, Ravishashidhar Vavilala
, Alex M. Szpilman

نتاج البحث: نشر في مجلة › مقالة › مراجعة النظراء

8 اقتباسات (Scopus)

ملخص

A fluorinated and a non-fluorinated axially chiral 1,8-diarylnaphthalene ligand have been synthesized through an Ullmann and Suzuki coupling reaction based strategy. A practical methodology for the successful chiral resolution of the newly synthesized catechol based moiety is presented. We also disclose the preliminary application of these axially chiral molecules as ligands in asymmetric transformation reactions.

اللغة الأصلية	الإنجليزيّة
الصفحات (من إلى)	79-84
عدد الصفحات	6
دورية	Tetrahedron Asymmetry
مستوى الصوت	26
رقم الإصدار	2-3
المعرِّفات الرقمية للأشياء	https://doi.org/10.1016/j.tetasy.2014.12.008
حالة النشر	نُشِر - 15 فبراير 2015
منشور خارجيًا	نعم

الوصول إلى المستند

10.1016/j.tetasy.2014.12.008

الملفات والروابط الأخرى

Link to publication in Scopus

قم بذكر هذا

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title = "Synthesis of axially chiral 1,8-diarylnaphthalene ligands and application in asymmetric catalysis: An intriguing fluorine effect",

abstract = "A fluorinated and a non-fluorinated axially chiral 1,8-diarylnaphthalene ligand have been synthesized through an Ullmann and Suzuki coupling reaction based strategy. A practical methodology for the successful chiral resolution of the newly synthesized catechol based moiety is presented. We also disclose the preliminary application of these axially chiral molecules as ligands in asymmetric transformation reactions.",

author = "Harisadhan Ghosh and Ravishashidhar Vavilala and Szpilman, \{Alex M.\}",

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T1 - Synthesis of axially chiral 1,8-diarylnaphthalene ligands and application in asymmetric catalysis

T2 - An intriguing fluorine effect

AU - Ghosh, Harisadhan

AU - Vavilala, Ravishashidhar

AU - Szpilman, Alex M.

PY - 2015/2/15

Y1 - 2015/2/15

N2 - A fluorinated and a non-fluorinated axially chiral 1,8-diarylnaphthalene ligand have been synthesized through an Ullmann and Suzuki coupling reaction based strategy. A practical methodology for the successful chiral resolution of the newly synthesized catechol based moiety is presented. We also disclose the preliminary application of these axially chiral molecules as ligands in asymmetric transformation reactions.

AB - A fluorinated and a non-fluorinated axially chiral 1,8-diarylnaphthalene ligand have been synthesized through an Ullmann and Suzuki coupling reaction based strategy. A practical methodology for the successful chiral resolution of the newly synthesized catechol based moiety is presented. We also disclose the preliminary application of these axially chiral molecules as ligands in asymmetric transformation reactions.

UR - https://www.scopus.com/pages/publications/84922188162

U2 - 10.1016/j.tetasy.2014.12.008

DO - 10.1016/j.tetasy.2014.12.008

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AN - SCOPUS:84922188162

SN - 0957-4166

VL - 26

SP - 79

EP - 84

JO - Tetrahedron Asymmetry

JF - Tetrahedron Asymmetry

IS - 2-3

ER -

Synthesis of axially chiral 1,8-diarylnaphthalene ligands and application in asymmetric catalysis: An intriguing fluorine effect

ملخص

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الملفات والروابط الأخرى

بصمة

قم بذكر هذا