Stereospecificity of the β-Hydroxyl Elimination from the (Hydroxyalkyl)chromium Complex (H2O)5Cr-CH(CH3)CH(CH3)OH2+

Haim Cohen; Alexander Feldman; Ruth Ish-Shalom; Dan Meyerstein

doi:10.1021/ja00014a023

Stereospecificity of the β-Hydroxyl Elimination from the (Hydroxyalkyl)chromium Complex (H₂O)₅Cr-CH(CH₃)CH(CH₃)OH²⁺

Haim Cohen
, Alexander Feldman
, Ruth Ish-Shalom
, Dan Meyerstein

نتاج البحث: نشر في مجلة › مقالة › مراجعة النظراء

16 اقتباسات (Scopus)

ملخص

The reaction of the aliphatic free radical *CH(CH₃)CH(OH)CH₃ (formed by *OH addition to cis-/trans-2-butene or by hydrogen abstraction from 2-butanol by *OH free radicals) with chromous ions in aqueous solutions was investigated. The radical reacts with Cr are also reported; the results indicate that methyl substituents considerably affect the rate of β-elimination reactions.

اللغة الأصلية	الإنجليزيّة
الصفحات (من إلى)	5292-5299
عدد الصفحات	8
دورية	Journal of the American Chemical Society
مستوى الصوت	113
رقم الإصدار	14
المعرِّفات الرقمية للأشياء	https://doi.org/10.1021/ja00014a023
حالة النشر	نُشِر - 1 يوليو 1991
منشور خارجيًا	نعم

الوصول إلى المستند

10.1021/ja00014a023

الملفات والروابط الأخرى

Link to publication in Scopus

قم بذكر هذا

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title = "Stereospecificity of the β-Hydroxyl Elimination from the (Hydroxyalkyl)chromium Complex (H2O)5Cr-CH(CH3)CH(CH3)OH2+ ",

abstract = "The reaction of the aliphatic free radical *CH(CH3)CH(OH)CH3 (formed by *OH addition to cis-/trans-2-butene or by hydrogen abstraction from 2-butanol by *OH free radicals) with chromous ions in aqueous solutions was investigated. The radical reacts with Cr are also reported; the results indicate that methyl substituents considerably affect the rate of β-elimination reactions.",

author = "Haim Cohen and Alexander Feldman and Ruth Ish-Shalom and Dan Meyerstein",

year = "1991",

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doi = "10.1021/ja00014a023",

language = "אנגלית",

volume = "113",

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journal = "Journal of the American Chemical Society",

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Stereospecificity of the β-Hydroxyl Elimination from the (Hydroxyalkyl)chromium Complex (H₂O)₅Cr-CH(CH₃)CH(CH₃)OH²⁺ . / Cohen, Haim; Feldman, Alexander; Ish-Shalom, Ruth وآخرون.
في: Journal of the American Chemical Society, المجلد 113, رقم 14, 01.07.1991, صفحة 5292-5299.

نتاج البحث: نشر في مجلة › مقالة › مراجعة النظراء

TY - JOUR

T1 - Stereospecificity of the β-Hydroxyl Elimination from the (Hydroxyalkyl)chromium Complex (H2O)5Cr-CH(CH3)CH(CH3)OH2+

AU - Cohen, Haim

AU - Feldman, Alexander

AU - Ish-Shalom, Ruth

AU - Meyerstein, Dan

PY - 1991/7/1

Y1 - 1991/7/1

N2 - The reaction of the aliphatic free radical *CH(CH3)CH(OH)CH3 (formed by *OH addition to cis-/trans-2-butene or by hydrogen abstraction from 2-butanol by *OH free radicals) with chromous ions in aqueous solutions was investigated. The radical reacts with Cr are also reported; the results indicate that methyl substituents considerably affect the rate of β-elimination reactions.

AB - The reaction of the aliphatic free radical *CH(CH3)CH(OH)CH3 (formed by *OH addition to cis-/trans-2-butene or by hydrogen abstraction from 2-butanol by *OH free radicals) with chromous ions in aqueous solutions was investigated. The radical reacts with Cr are also reported; the results indicate that methyl substituents considerably affect the rate of β-elimination reactions.

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DO - 10.1021/ja00014a023

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AN - SCOPUS:0011408893

SN - 0002-7863

VL - 113

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JO - Journal of the American Chemical Society

JF - Journal of the American Chemical Society

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