Selectivity of Outer-Sphere Electron-Transfer Reactions. 3

Haim Cohen; Shlomo Efrima; Dan Meyerstein; Mordechi Nutkovich; Karl Wieghardt

doi:10.1021/ic00146a023

Selectivity of Outer-Sphere Electron-Transfer Reactions. 3

Haim Cohen
, Shlomo Efrima
, Dan Meyerstein
, Mordechi Nutkovich
, Karl Wieghardt

نتاج البحث: نشر في مجلة › مقالة › مراجعة النظراء

4 اقتباسات (Scopus)

ملخص

The study of the kinetics of the reductions of a series of binuclear (μ-carboxylato)bis(μ-hydroxo)bis[triamminecobalt(III)] complexes has been extended to more powerful reducing agents. It was found that for very exothermic reactions the selectivity becomes independent of the redox potential of the reductant. The results are analyzed in the frame of the full Marcus formalism.

اللغة الأصلية	الإنجليزيّة
الصفحات (من إلى)	688-690
عدد الصفحات	3
دورية	Inorganic Chemistry
مستوى الصوت	22
رقم الإصدار	4
المعرِّفات الرقمية للأشياء	https://doi.org/10.1021/ic00146a023
حالة النشر	نُشِر - فبراير 1983
منشور خارجيًا	نعم

الوصول إلى المستند

10.1021/ic00146a023

الملفات والروابط الأخرى

Link to publication in Scopus

قم بذكر هذا

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title = "Selectivity of Outer-Sphere Electron-Transfer Reactions. 3",

abstract = "The study of the kinetics of the reductions of a series of binuclear (μ-carboxylato)bis(μ-hydroxo)bis[triamminecobalt(III)] complexes has been extended to more powerful reducing agents. It was found that for very exothermic reactions the selectivity becomes independent of the redox potential of the reductant. The results are analyzed in the frame of the full Marcus formalism.",

author = "Haim Cohen and Shlomo Efrima and Dan Meyerstein and Mordechi Nutkovich and Karl Wieghardt",

year = "1983",

month = feb,

doi = "10.1021/ic00146a023",

language = "אנגלית",

volume = "22",

pages = "688--690",

journal = "Inorganic Chemistry",

issn = "0020-1669",

publisher = "American Chemical Society",

number = "4",

}

TY - JOUR

T1 - Selectivity of Outer-Sphere Electron-Transfer Reactions. 3

AU - Cohen, Haim

AU - Efrima, Shlomo

AU - Meyerstein, Dan

AU - Nutkovich, Mordechi

AU - Wieghardt, Karl

PY - 1983/2

Y1 - 1983/2

N2 - The study of the kinetics of the reductions of a series of binuclear (μ-carboxylato)bis(μ-hydroxo)bis[triamminecobalt(III)] complexes has been extended to more powerful reducing agents. It was found that for very exothermic reactions the selectivity becomes independent of the redox potential of the reductant. The results are analyzed in the frame of the full Marcus formalism.

AB - The study of the kinetics of the reductions of a series of binuclear (μ-carboxylato)bis(μ-hydroxo)bis[triamminecobalt(III)] complexes has been extended to more powerful reducing agents. It was found that for very exothermic reactions the selectivity becomes independent of the redox potential of the reductant. The results are analyzed in the frame of the full Marcus formalism.

UR - https://www.scopus.com/pages/publications/4243547758

U2 - 10.1021/ic00146a023

DO - 10.1021/ic00146a023

M3 - ???researchoutput.researchoutputtypes.contributiontojournal.article???

AN - SCOPUS:4243547758

SN - 0020-1669

VL - 22

SP - 688

EP - 690

JO - Inorganic Chemistry

JF - Inorganic Chemistry

IS - 4

ER -

Selectivity of Outer-Sphere Electron-Transfer Reactions. 3

ملخص

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الملفات والروابط الأخرى

بصمة

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