Reduction of maleate and fumarate by the CO2.- anion radical

Osnat Schutz; Dan Meyerstein

doi:10.1016/j.tetlet.2005.12.042

Reduction of maleate and fumarate by the CO_2.- anion radical

Osnat Schutz
, Dan Meyerstein

Department of Chemical Sciences

نتاج البحث: نشر في مجلة › مقالة › مراجعة النظراء

12 اقتباسات (Scopus)

ملخص

The radical anion CO₂^.- reacts with fumarate and maleate at pH 5.3 mainly via electron transfer. The final products are a mixture of (^-O₂CCH₂-)₂, trans-( ^-O₂CCH)₂ and products with higher molecular weight. At higher pHs, the yield of fumarate and succinate decreases. The results suggest that though the radical anions formed by the reduction of fumarate and maleate have different structures, the final products are probably the same.

اللغة الأصلية	الإنجليزيّة
الصفحات (من إلى)	1093-1096
عدد الصفحات	4
دورية	Tetrahedron Letters
مستوى الصوت	47
رقم الإصدار	7
المعرِّفات الرقمية للأشياء	https://doi.org/10.1016/j.tetlet.2005.12.042
حالة النشر	نُشِر - 13 فبراير 2006

الوصول إلى المستند

10.1016/j.tetlet.2005.12.042

الملفات والروابط الأخرى

Link to publication in Scopus

قم بذكر هذا

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title = "Reduction of maleate and fumarate by the CO2.- anion radical",

abstract = "The radical anion CO2.- reacts with fumarate and maleate at pH 5.3 mainly via electron transfer. The final products are a mixture of (-O2CCH2-)2, trans-( -O2CCH)2 and products with higher molecular weight. At higher pHs, the yield of fumarate and succinate decreases. The results suggest that though the radical anions formed by the reduction of fumarate and maleate have different structures, the final products are probably the same.",

author = "Osnat Schutz and Dan Meyerstein",

note = "Funding Information: This study was supported in part by a grant from the Budgeting and Planning Committee of The Council of Higher Education and the Israel Atomic Energy Commission. D.M. wishes to express his thanks to Mrs. Irene Evans for her ongoing interest and support.",

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T1 - Reduction of maleate and fumarate by the CO2.- anion radical

AU - Schutz, Osnat

AU - Meyerstein, Dan

N1 - Funding Information: This study was supported in part by a grant from the Budgeting and Planning Committee of The Council of Higher Education and the Israel Atomic Energy Commission. D.M. wishes to express his thanks to Mrs. Irene Evans for her ongoing interest and support.

PY - 2006/2/13

Y1 - 2006/2/13

N2 - The radical anion CO2.- reacts with fumarate and maleate at pH 5.3 mainly via electron transfer. The final products are a mixture of (-O2CCH2-)2, trans-( -O2CCH)2 and products with higher molecular weight. At higher pHs, the yield of fumarate and succinate decreases. The results suggest that though the radical anions formed by the reduction of fumarate and maleate have different structures, the final products are probably the same.

AB - The radical anion CO2.- reacts with fumarate and maleate at pH 5.3 mainly via electron transfer. The final products are a mixture of (-O2CCH2-)2, trans-( -O2CCH)2 and products with higher molecular weight. At higher pHs, the yield of fumarate and succinate decreases. The results suggest that though the radical anions formed by the reduction of fumarate and maleate have different structures, the final products are probably the same.

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JO - Tetrahedron Letters

JF - Tetrahedron Letters

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