Polaronic Mechanism of Vibronic Localization in Mixed-Valence Cation Radicals with a Non-Conjugated Chromophore on the Bridge

Keyphrases

• Electron Transfer 100%
• Vibronic 100%
• Radical Cation 100%
• Mixed Valence 100%
• Chromophore 100%
• Non-conjugated 100%
• Mixed-valence Compounds 50%
• II-VI 50%
• Localized Charges 50%
• Polaronic Effect 50%
• Allyl Group 50%
• Allyl 25%
• Redox Sites 25%
• Electric Field (E-field) 25%
• Butane 25%
• Intramolecular Electron Transfer 25%
• Potential Barrier 25%
• Ab Initio Calculations 25%
• Vibronic Coupling 25%
• Charge Localization 25%
• Transfer Parameters 25%
• Localized Type 25%
• Transition Structure 25%
• Induced Dipole Moment 25%

Chemistry

• Radical Cation 100%
• Mixed Valence 100%
• Electron Transport 100%
• Chromophore 100%
• Allyl Group 40%
• Dipole Moment 20%
• Electric Field 20%
• Ab Initio Calculation 20%
• Vibronic Coupling 20%
• Potential Barrier 20%