On the reactions of methyl radicals with nitrilotris(methylenephosphonic-acid) complexes in aqueous solutions

Guy Yardeni, Dan Meyerstein, Lioubov Kats, Haim Cohen, Israel Zilbermann, Eric Maimon

نتاج البحث: نشر في مجلةمقالةمراجعة النظراء

4 اقتباسات (Scopus)

ملخص

The reactions of methyl radicals with MII-(ntp)(H2O)2 complexes were studied. The formation of an unstable intermediate (ntp)(H2O)MIII-CH3 is observed. This reaction is an equilibrium process, i.e. the MIII-C bond decomposes via homolysis. The (ntp)(H2O)MIII-CH3 complexes isomerize to a more stable form. The results compared to those obtained in analogous reactions of the MII-(nta)(H2O)2 complexes were shown to be similar with one exception–for the nta complexes no isomerization process is observed.

اللغة الأصليةالإنجليزيّة
الصفحات (من إلى)3445-3457
عدد الصفحات13
دوريةJournal of Coordination Chemistry
مستوى الصوت72
رقم الإصدار22-24
المعرِّفات الرقمية للأشياء
حالة النشرنُشِر - 17 ديسمبر 2019

بصمة

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