Mechanism of oxidation of aquated copper(II) ions by hydroxyl free radicals. A high-pressure pulse-radiolysis experiment

Haim Cohen; Rudi van Eldik; Mohamed Masarwa; Dan Meyerstein

doi:10.1016/S0020-1693(00)91905-4

Mechanism of oxidation of aquated copper(II) ions by hydroxyl free radicals. A high-pressure pulse-radiolysis experiment

Haim Cohen
, Rudi van Eldik
, Mohamed Masarwa
, Dan Meyerstein

نتاج البحث: نشر في مجلة › مقالة › مراجعة النظراء

13 اقتباسات (Scopus)

ملخص

The pressure dependence of the reaction Cu(H₂O)_m²⁺ + ^·OH→Cu(III)_aq+OH^-, studied using pulse-radiolysis techniques at pressures up to 150 MPa, suggests a rate-determining ligand interchange mechanism.

اللغة الأصلية	الإنجليزيّة
الصفحات (من إلى)	31-34
عدد الصفحات	4
دورية	Inorganica Chimica Acta
مستوى الصوت	177
رقم الإصدار	1
المعرِّفات الرقمية للأشياء	https://doi.org/10.1016/S0020-1693(00)91905-4
حالة النشر	نُشِر - 1 نوفمبر 1990
منشور خارجيًا	نعم

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10.1016/S0020-1693(00)91905-4

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Link to publication in Scopus

قم بذكر هذا

@article{391fee68f3234a148167eb71c9f6cedc,

title = "Mechanism of oxidation of aquated copper(II) ions by hydroxyl free radicals. A high-pressure pulse-radiolysis experiment",

abstract = "The pressure dependence of the reaction Cu(H2O)m2+ + ·OH→Cu(III)aq+OH-, studied using pulse-radiolysis techniques at pressures up to 150 MPa, suggests a rate-determining ligand interchange mechanism.",

author = "Haim Cohen and \{van Eldik\}, Rudi and Mohamed Masarwa and Dan Meyerstein",

note = "Funding Information: This study was supported in part by a grant from the Israel Atomic Energy Commission and the Planning and Granting Committee of the Council of Higher Education, Jerusalem. R.v.E. acknowledges financial support from the Deutsche Forschungs-gemeinschafta nd the Volkswagen-Stiftung. The authors gratefully acknowledges upport from the German-Israeli Foundation for Scientific Research and Development. D.M. wishes to expressh is thanks to Mrs Irene Evans for her continued interest and support.",

year = "1990",

month = nov,

day = "1",

doi = "10.1016/S0020-1693(00)91905-4",

language = "אנגלית",

volume = "177",

pages = "31--34",

journal = "Inorganica Chimica Acta",

issn = "0020-1693",

publisher = "Elsevier B.V.",

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TY - JOUR

T1 - Mechanism of oxidation of aquated copper(II) ions by hydroxyl free radicals. A high-pressure pulse-radiolysis experiment

AU - Cohen, Haim

AU - van Eldik, Rudi

AU - Masarwa, Mohamed

AU - Meyerstein, Dan

N1 - Funding Information: This study was supported in part by a grant from the Israel Atomic Energy Commission and the Planning and Granting Committee of the Council of Higher Education, Jerusalem. R.v.E. acknowledges financial support from the Deutsche Forschungs-gemeinschafta nd the Volkswagen-Stiftung. The authors gratefully acknowledges upport from the German-Israeli Foundation for Scientific Research and Development. D.M. wishes to expressh is thanks to Mrs Irene Evans for her continued interest and support.

PY - 1990/11/1

Y1 - 1990/11/1

N2 - The pressure dependence of the reaction Cu(H2O)m2+ + ·OH→Cu(III)aq+OH-, studied using pulse-radiolysis techniques at pressures up to 150 MPa, suggests a rate-determining ligand interchange mechanism.

AB - The pressure dependence of the reaction Cu(H2O)m2+ + ·OH→Cu(III)aq+OH-, studied using pulse-radiolysis techniques at pressures up to 150 MPa, suggests a rate-determining ligand interchange mechanism.

UR - https://www.scopus.com/pages/publications/0001949580

U2 - 10.1016/S0020-1693(00)91905-4

DO - 10.1016/S0020-1693(00)91905-4

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AN - SCOPUS:0001949580

SN - 0020-1693

VL - 177

SP - 31

EP - 34

JO - Inorganica Chimica Acta

JF - Inorganica Chimica Acta

IS - 1

ER -

Mechanism of oxidation of aquated copper(II) ions by hydroxyl free radicals. A high-pressure pulse-radiolysis experiment

ملخص

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