Jetting liquid marbles: Study of the Taylor instability in immersed marbles

The behavior of liquid marbles encapsulated with various powders, immersed in oil, and exposed to a uniform DC field was investigated. At some critical value of the electric field, the Taylor instability of the marble shape took place, accompanied by the appearance of a cone and jetting a small droplet. The squared critical electric field was linear dependent on inverse of the size parameter of the marble. In some cases, the extrapolation of this linear dependence to the zero field gave the finite value of the spherical marble radius corresponding to the Rayleigh limit that meant that the marbles were charged. Lycopodium-coated marbles remained neutral under the action of a DC field, as well as a pure water droplet. Therefore, charging marbles is determined by their powder coverage. The data on effective surface tension at marble-oil interfaces were extracted from the above linear dependence for the uncharged marble. The effective surface tension was measured in parallel by the capillary rise method.