Effect of pH and Acetate on the Rate of Hydrolysis of the Chromium-Carbon Bond in (α-Hydroxyalkyl)chromium(III) Complexes

Haim Cohen; Dan Meyerstein

doi:10.1021/ic00169a018

Effect of pH and Acetate on the Rate of Hydrolysis of the Chromium-Carbon Bond in (α-Hydroxyalkyl)chromium(III) Complexes

نتاج البحث: نشر في مجلة › مقالة › مراجعة النظراء

24 اقتباسات (Scopus)

ملخص

The kinetics of the hydrolysis of [(H₂0)₅CrC(CH₃)₂0H]²⁺in the pH range 0.0-5.6 are reported. The results indicate that the hydrolysis reaction is faster for [(H₂0)_5-n(0H)nCrC(CH₃)₂0H]^2-n. Furthermore, the rate of hydrolysis of [(H₂0)₅CrCR1R₂OH]²⁺is accelerated by acetate anions. The mechanistic implications of these results are discussed in detail.

اللغة الأصلية	الإنجليزيّة
الصفحات (من إلى)	84-87
عدد الصفحات	4
دورية	Inorganic Chemistry
مستوى الصوت	23
رقم الإصدار	1
المعرِّفات الرقمية للأشياء	https://doi.org/10.1021/ic00169a018
حالة النشر	نُشِر - فبراير 1984
منشور خارجيًا	نعم

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10.1021/ic00169a018

الملفات والروابط الأخرى

Link to publication in Scopus

قم بذكر هذا

@article{d13c6a3fe0f54490ba11fa797515bbcc,

title = "Effect of pH and Acetate on the Rate of Hydrolysis of the Chromium-Carbon Bond in (α-Hydroxyalkyl)chromium(III) Complexes",

abstract = "The kinetics of the hydrolysis of [(H20)5CrC(CH3)20H]2+in the pH range 0.0-5.6 are reported. The results indicate that the hydrolysis reaction is faster for [(H20)5-n(0H)nCrC(CH3)20H]2-n. Furthermore, the rate of hydrolysis of [(H20)5CrCR1R2OH]2+is accelerated by acetate anions. The mechanistic implications of these results are discussed in detail.",

author = "Haim Cohen and Dan Meyerstein",

year = "1984",

month = feb,

doi = "10.1021/ic00169a018",

language = "אנגלית",

volume = "23",

pages = "84--87",

journal = "Inorganic Chemistry",

issn = "0020-1669",

publisher = "American Chemical Society",

number = "1",

}

TY - JOUR

T1 - Effect of pH and Acetate on the Rate of Hydrolysis of the Chromium-Carbon Bond in (α-Hydroxyalkyl)chromium(III) Complexes

AU - Cohen, Haim

AU - Meyerstein, Dan

PY - 1984/2

Y1 - 1984/2

N2 - The kinetics of the hydrolysis of [(H20)5CrC(CH3)20H]2+in the pH range 0.0-5.6 are reported. The results indicate that the hydrolysis reaction is faster for [(H20)5-n(0H)nCrC(CH3)20H]2-n. Furthermore, the rate of hydrolysis of [(H20)5CrCR1R2OH]2+is accelerated by acetate anions. The mechanistic implications of these results are discussed in detail.

AB - The kinetics of the hydrolysis of [(H20)5CrC(CH3)20H]2+in the pH range 0.0-5.6 are reported. The results indicate that the hydrolysis reaction is faster for [(H20)5-n(0H)nCrC(CH3)20H]2-n. Furthermore, the rate of hydrolysis of [(H20)5CrCR1R2OH]2+is accelerated by acetate anions. The mechanistic implications of these results are discussed in detail.

UR - https://www.scopus.com/pages/publications/4243208904

U2 - 10.1021/ic00169a018

DO - 10.1021/ic00169a018

M3 - ???researchoutput.researchoutputtypes.contributiontojournal.article???

AN - SCOPUS:4243208904

SN - 0020-1669

VL - 23

SP - 84

EP - 87

JO - Inorganic Chemistry

JF - Inorganic Chemistry

IS - 1

ER -

Effect of pH and Acetate on the Rate of Hydrolysis of the Chromium-Carbon Bond in (α-Hydroxyalkyl)chromium(III) Complexes

ملخص

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