Chromium-Carbon Bonds in Aqueous Solutions. A Pulse Radiolytic Study

H. Cohen; D. Meyerstein

doi:10.1021/ic50140a027

Chromium-Carbon Bonds in Aqueous Solutions. A Pulse Radiolytic Study

H. Cohen, D. Meyerstein

نتاج البحث: نشر في مجلة › مقالة › مراجعة النظراء

137 اقتباسات (Scopus)

ملخص

The specific rates of reaction of 16 aliphatic radicals with Cr(H₂O)₆²⁺ were determined. The absorption spectra due to the chromium-carbon bonds in the products of these reactions were measured. The specific rates of aquation of these complexes as a function of pH were determined. The effects of the structure of the aliphatic radicals on these spectra and specific rates of reactions are discussed in detail. It is shown that chromium induces water elimination when a β-hydroxyl group is present.

اللغة الأصلية	الإنجليزيّة
الصفحات (من إلى)	2434-2443
عدد الصفحات	10
دورية	Inorganic Chemistry
مستوى الصوت	13
رقم الإصدار	10
المعرِّفات الرقمية للأشياء	https://doi.org/10.1021/ic50140a027
حالة النشر	نُشِر - 1 أكتوبر 1974
منشور خارجيًا	نعم

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10.1021/ic50140a027

الملفات والروابط الأخرى

Link to publication in Scopus

قم بذكر هذا

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title = "Chromium-Carbon Bonds in Aqueous Solutions. A Pulse Radiolytic Study",

abstract = "The specific rates of reaction of 16 aliphatic radicals with Cr(H2O)62+ were determined. The absorption spectra due to the chromium-carbon bonds in the products of these reactions were measured. The specific rates of aquation of these complexes as a function of pH were determined. The effects of the structure of the aliphatic radicals on these spectra and specific rates of reactions are discussed in detail. It is shown that chromium induces water elimination when a β-hydroxyl group is present.",

author = "H. Cohen and D. Meyerstein",

year = "1974",

month = oct,

day = "1",

doi = "10.1021/ic50140a027",

language = "אנגלית",

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journal = "Inorganic Chemistry",

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T1 - Chromium-Carbon Bonds in Aqueous Solutions. A Pulse Radiolytic Study

AU - Cohen, H.

AU - Meyerstein, D.

PY - 1974/10/1

Y1 - 1974/10/1

N2 - The specific rates of reaction of 16 aliphatic radicals with Cr(H2O)62+ were determined. The absorption spectra due to the chromium-carbon bonds in the products of these reactions were measured. The specific rates of aquation of these complexes as a function of pH were determined. The effects of the structure of the aliphatic radicals on these spectra and specific rates of reactions are discussed in detail. It is shown that chromium induces water elimination when a β-hydroxyl group is present.

AB - The specific rates of reaction of 16 aliphatic radicals with Cr(H2O)62+ were determined. The absorption spectra due to the chromium-carbon bonds in the products of these reactions were measured. The specific rates of aquation of these complexes as a function of pH were determined. The effects of the structure of the aliphatic radicals on these spectra and specific rates of reactions are discussed in detail. It is shown that chromium induces water elimination when a β-hydroxyl group is present.

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U2 - 10.1021/ic50140a027

DO - 10.1021/ic50140a027

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AN - SCOPUS:0000938524

SN - 0020-1669

VL - 13

SP - 2434

EP - 2443

JO - Inorganic Chemistry

JF - Inorganic Chemistry

IS - 10

ER -

Chromium-Carbon Bonds in Aqueous Solutions. A Pulse Radiolytic Study

ملخص

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الملفات والروابط الأخرى

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