ملخص
Vinyl azides react with boron trifluoride activated Koser's hypervalent iodine reagent to afford azido-enolonium species. These previously unknown azido-enolonium species react efficiently with aromatic compounds, allyltrimethylsilane, and azoles under mild conditions, with no need for a transition-metal catalyst, forming C-C and C-N bonds to give a variety of α-functionalized ketones. The intermediacy of the proposed azido-enolonium species is supported by spectroscopic studies.
| اللغة الأصلية | الإنجليزيّة |
|---|---|
| الصفحات (من إلى) | 768-771 |
| عدد الصفحات | 4 |
| دورية | Organic Letters |
| مستوى الصوت | 22 |
| رقم الإصدار | 3 |
| المعرِّفات الرقمية للأشياء | |
| حالة النشر | نُشِر - 7 فبراير 2020 |