Amine-tetrachloromethane charge transfer complexes: a structural and computational study

Abhaya K. Mishra, Galit Parvari, Irit Cohen, Natalia Fridman, Yoav Eichen, Alex M. Szpilman

نتاج البحث: نشر في مجلةمقالةمراجعة النظراء

3 اقتباسات (Scopus)

ملخص

Amine-tetrachloromethane charge-transfer complexes have recently been shown to be useful intermediates in transition-metal free solar light-assisted organic synthetic chemistry. Of particular promise is the complex of 1,4-diazabicyclo[2.2.2]octane (DABCO) which may serve as a starting point for several potential reactions involving oxidation of organic compounds. Here we disclose the crystal structure of the [DABCO•••CCl4] complex, and computational studies of two possible complex structures in their ground state, as well as in their first singlet and first triplet excited states.

اللغة الأصليةالإنجليزيّة
الصفحات (من إلى)2082-2089
عدد الصفحات8
دوريةJournal of Coordination Chemistry
مستوى الصوت71
رقم الإصدار11-13
المعرِّفات الرقمية للأشياء
حالة النشرنُشِر - 3 يوليو 2018

بصمة

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