A novel formyl complex [(H2O)5CrCHO]2+. A pulse radiolysis study

Haim Cohen; Dan Meyerstein; Alan J. Shusterman; Mathania Weiss

doi:10.1039/c39850000424

A novel formyl complex [(H²O)₅CrCHO]²⁺. A pulse radiolysis study

Haim Cohen
, Dan Meyerstein
, Alan J. Shusterman
, Mathania Weiss

نتاج البحث: نشر في مجلة › مقالة › مراجعة النظراء

4 اقتباسات (Scopus)

ملخص

The formyl complex [(H₂O)₅CrCHO]²⁺ is formed in aqueous solution via the reaction sequence: Cr²⁺(aq.) + ·CH(OH)₂ → [(H₂O)₅CrCH(OH) ₂]²⁺ → [(H₂O)₅CrCHO ⁺²] + H₂O, and reduces formaldehyde (k = 1 mol ^-1 dm³ s^-1), yielding CO + CH₃OH; the spectra of [(H₂O)₅CrCH(OH)₂]²⁺ and [(H₂O)₅CrCHO]²⁺ are reported.

اللغة الأصلية	الإنجليزيّة
الصفحات (من إلى)	424-425
عدد الصفحات	2
دورية	Journal of the Chemical Society D: Chemical Communications
رقم الإصدار	7
المعرِّفات الرقمية للأشياء	https://doi.org/10.1039/c39850000424
حالة النشر	نُشِر - 1985
منشور خارجيًا	نعم

الوصول إلى المستند

10.1039/c39850000424

الملفات والروابط الأخرى

Link to publication in Scopus

قم بذكر هذا

@article{0049256e79ae460bb434831bffdf8f22,

title = "A novel formyl complex [(H2O)5CrCHO]2+. A pulse radiolysis study",

abstract = "The formyl complex [(H2O)5CrCHO]2+ is formed in aqueous solution via the reaction sequence: Cr2+(aq.) + ·CH(OH)2 → [(H2O)5CrCH(OH) 2]2+ → [(H2O)5CrCHO +2] + H2O, and reduces formaldehyde (k = 1 mol -1 dm3 s-1), yielding CO + CH3OH; the spectra of [(H2O)5CrCH(OH)2]2+ and [(H2O)5CrCHO]2+ are reported.",

author = "Haim Cohen and Dan Meyerstein and Shusterman, \{Alan J.\} and Mathania Weiss",

year = "1985",

doi = "10.1039/c39850000424",

language = "אנגלית",

pages = "424--425",

number = "7",

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TY - JOUR

T1 - A novel formyl complex [(H2O)5CrCHO]2+. A pulse radiolysis study

AU - Cohen, Haim

AU - Meyerstein, Dan

AU - Shusterman, Alan J.

AU - Weiss, Mathania

PY - 1985

Y1 - 1985

N2 - The formyl complex [(H2O)5CrCHO]2+ is formed in aqueous solution via the reaction sequence: Cr2+(aq.) + ·CH(OH)2 → [(H2O)5CrCH(OH) 2]2+ → [(H2O)5CrCHO +2] + H2O, and reduces formaldehyde (k = 1 mol -1 dm3 s-1), yielding CO + CH3OH; the spectra of [(H2O)5CrCH(OH)2]2+ and [(H2O)5CrCHO]2+ are reported.

AB - The formyl complex [(H2O)5CrCHO]2+ is formed in aqueous solution via the reaction sequence: Cr2+(aq.) + ·CH(OH)2 → [(H2O)5CrCH(OH) 2]2+ → [(H2O)5CrCHO +2] + H2O, and reduces formaldehyde (k = 1 mol -1 dm3 s-1), yielding CO + CH3OH; the spectra of [(H2O)5CrCH(OH)2]2+ and [(H2O)5CrCHO]2+ are reported.

UR - https://www.scopus.com/pages/publications/0040762461

U2 - 10.1039/c39850000424

DO - 10.1039/c39850000424

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AN - SCOPUS:0040762461

SN - 0022-4936

SP - 424

EP - 425

JO - Journal of the Chemical Society D: Chemical Communications

JF - Journal of the Chemical Society D: Chemical Communications

IS - 7